n-type silicon is made by adding a pentavalent impurity (such as phosphorus). Each dopant atom gives an extra free electron, so electrons are the majority carriers and holes the minority carriers. Only statement (c) matches.
(c)
Solutions to all 6 exercises of Chapter 14, Semiconductor Electronics: Materials, Devices and Simple Circuits (NCERT Class 12 Physics Part II, 2026-27): majority and minority carriers in n-type and p-type semiconductors, band gaps of carbon, silicon and germanium, diffusion in a p-n junction, forward bias, and output frequency of half-wave and full-wave rectifiers. All 6 questions are answered, with the key answer highlighted.
NCERT textbook Chapter 14 (PDF)
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n-type: pentavalent dopant (P, As), electrons are majority carriers. p-type: trivalent dopant (B, Al), holes are majority carriers. Forward bias lowers the potential barrier; reverse bias raises it. Band gaps: C (diamond) about 5.4 eV, Si about 1.1 eV, Ge about 0.7 eV.
n-type silicon is made by adding a pentavalent impurity (such as phosphorus). Each dopant atom gives an extra free electron, so electrons are the majority carriers and holes the minority carriers. Only statement (c) matches.
(c)
p-type material is made by adding a trivalent impurity (such as boron). Each dopant atom creates a hole, so holes are the majority carriers. Statement (d) is true.
(d)
Carbon (diamond) has the largest band gap (about 5.4 eV, an insulator), silicon about 1.1 eV and germanium about 0.7 eV. Going down the group, the band gap decreases.
(c)
Diffusion always happens from a region of higher concentration to lower concentration. There are many more holes in the p-region than in the n-region, so holes diffuse into the n-region. (The potential difference across the junction actually opposes this flow.)
(c)
In forward bias the applied voltage opposes the junction's built-in potential, so the barrier is lowered, the depletion layer narrows, and a large majority-carrier current flows.
(c)
Half-wave: 50 Hz. Full-wave: 100 Hz.

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